| چکیده انگلیسی مقاله |
The structural and dielectric properties of iron and bismuth co-substituted BaTiO3 ceramic with the formula: B0.95Bi0.05Ti1-xFexO3 for x=0.00 to 1.00, synthesis with solid state route, were characterized. The X-ray diffraction results show a tetragonal phase for x=0.00. While for x=0.40 to 0.80 we observed a coexistence of tree phase tetragonal, hexagonal and pseudo-cubic. And at x=1.00 only the pseudo-cubic phase is present and the other phase disappeared. The Raman results indicate the existence of tetragonal band for x≤0.40, and an appearance of characteristic bands of Fe3+ ions for more than 0.40 of Fe content. The SEM micrographs show an increase in grain size with the increase of Fe content and it reaches a maximum at x=0.40. And the Mossbauer spectroscopy indicates that our samples is paramagnetic at room temperature and that the Fe is oxidized under Fe3+ with no existence of Fe2+ and Fe4+ ions. The temperature dependence of dielectric permittivity was investigated in the frequency range from 20 Hz to 2MHz. The results show three dielectric relaxation phase transitions from a rhombohedral ferroelectric to orthorhombic ferroelectric (TR-O) then to a tetragonal ferroelectric phase (at TO-T), and finally to cubic paraelectric at the Curie temperature (TC). In addition, the temperature of phase transition shifted to the lower temperature with the increase of Fe content for all the phase transitions. And the maximum of dielectric permittivity increases for TR-O while for TT-O and Tm phases transitions, it reaches a maximum at x=0.60 and x=0.80 respectively and then decreases. |
| کلیدواژههای انگلیسی مقاله |
Structural,dielectric,BaTiO3,solid state,SEM,Mossbauer,paramagnetic,phase transition,curie temperature. |
| نویسندگان مقاله |
| Najwa Gouitaa
Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco
| Lamcharfi Taj-dine
Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco
| Bouayad Lamfaddal
Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco
| Abdi Farid
Signals, Systems and Components Laboratory (LSSC), Electrical Engineering Department, University Sidi Mohamed Ben Abdellah USMBA, FST. Fez, Imouzzer Road B.P. 2202, Morocco
| Mohamed Ounacer
Physic of Materials Laboratory, FST, University Sultan Moulay Slimane, BP 523,23000, Beni-Mellal, Morocco
| Mohammed Sajieddine
Physic of Materials Laboratory, FST, University Sultan Moulay Slimane, BP 523,23000, Beni-Mellal, Morocco
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