Analytical and Bioanalytical Chemistry Research، جلد ۳، شماره ۱، صفحات ۸۷-۹۹

عنوان فارسی
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عنوان انگلیسی Determination of Rhodium(III) Ions by Flame Atomic Absorption Spectrometry after Preconcentration with Modified Magnetic Activated Carbon
چکیده انگلیسی مقاله A new method for analysis of trace amount of Rh(III) ions by magnetic activated carbon modified with 2,3,5,6-tetra(2-pyridyl)pyrazine (MAC/TPPZ) as the magnetic sorbent has been proposed. The proposed adsorbent was found to be advantageous over conventional solid phase extraction (SPE) in terms of operational simplicity and low time-consuming. The experimental parameters affecting the extraction/preconcentration and determination of the analyte were systematically examined. In order to investigate the selectivity of this magnetic sorbent, the effect of a variety of ions on preconcentration and recovery of Rh(III) ions were also investigated. Under optimum conditions, the calibration graph was linear for the concentration range of 0.8-650 µg l-1. The limit of detection (LOD, 3Sb/m) and the relative standard deviation (RSD, n = 8, c = 50 µg l-1) were 0.1 µg l-1 and 3.6%, respectively. The maximum sorption capacity of the adsorbent for rhodium was found to be 21.6 mg g-1. The presented procedure was applied to monitoring rhodium in water and synthetic samples.
کلیدواژه‌های انگلیسی مقاله Spectrometry,Magnetic activated carbon,Rhodium,Nanocomposite

نویسندگان مقاله مریم فیاضی |
shahid bahonar university of kerman
سازمان اصلی تایید شده: دانشگاه شهید باهنر (Shahid bahonar university)

مسعود قانعی مطلق | ghanei motlagh
shahid bahonar university of kerman
سازمان اصلی تایید شده: دانشگاه شهید باهنر (Shahid bahonar university)

محمد علی طاهر | mohammad ali
shahid bahonar university of kerman
سازمان اصلی تایید شده: دانشگاه شهید باهنر (Shahid bahonar university)

راضیه فیاضی |
islamic azad university
سازمان اصلی تایید شده: دانشگاه آزاد اسلامی علوم و تحقیقات (Islamic azad university science and research branch)


نشانی اینترنتی http://www.analchemres.org/article_14570_bf208aef2eb24617a5bc9f3fcd6a444a.pdf
فایل مقاله اشکال در دسترسی به فایل - ./files/site1/rds_journals/378/article-378-332572.pdf
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زبان مقاله منتشر شده en
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