Iranian Journal of Chemistry and Chemical Engineering، جلد ۳۹، شماره ۵، صفحات ۱۱-۱۹
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عنوان انگلیسی Convenient and Robust Metal-Free Synthesis of Benzazole-2-Ones Through the Reaction of Aniline Derivatives and Sodium Cyanate in Aqueous Medium
چکیده انگلیسی مقاله Benzazole-2-ones (benzimidazolones, benzothiazolones, benzoxazolones) are important derivatives of benzazole compounds that exist widely in many biologically and pharmaceutically active molecules. Furthermore, benzazole-2-one derivatives also have many applications in agrochemical and material science. Herein, a novel, practical and green synthesis of titled compounds by the reaction of aniline derivatives with inexpensive and easily accessible sodium cyanate has been reported. Good to excellent yields of products have been obtained under catalyst- and ligand-free conditions in water as solvent. This procedure avoids the use of time-consuming and tedious column chromatography and the products were easily isolated by simple extraction followed by washing with dichloromethane.
کلیدواژه‌های انگلیسی مقاله benzazole-2-ones,Benzimidazolones, benzothiazolones,benzoxazolones,sodium cyanate,Green Chemistry,water,Synthesis
نویسندگان مقاله Esmail Vessally |
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN

Somayeh Mohammadi |
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN

Morteza Abdoli |
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN

Akram Hosseinian |
School of Engineering Science, College of Engineering, University of Tehran, Tehran, I.R. IRAN

Parisa Ojaghloo |
Department of Chemistry, Payame Noor University, Tehran, I.R. IRAN

نشانی اینترنتی https://ijcce.ac.ir/article_36288_52716342806f57045441185ecf1aa7c2.pdf
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