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Iranian Journal of Chemistry and Chemical Engineering، جلد ۳۹، شماره ۶، صفحات ۲۹-۴۲
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| عنوان فارسی |
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| چکیده فارسی مقاله |
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| کلیدواژه‌های فارسی مقاله |
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| عنوان انگلیسی |
Methylene Blue Adsorption by Magnesium Oxide Nanoparticles Immobilized with Chitosan (CS-MgONP): Response Surface Methodology, Isotherm, Kinetics and Thermodynamic Studies |
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| چکیده انگلیسی مقاله |
In this research, a chitosan-immobilized magnesium oxide nanoparticle (CS-MgONP) was synthesized to evaluate it as a prospective adsorbent for a cationic Methylene Blue (MB) dye. For the synthesized adsorbent, functional groups were analyzed through Fourier transform InfraRed (FT-IR) spectroscopy. X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) were used to identify the structural and morphological observations. The evaluation of process parameters such as pH (5-9), CS-MgONP dosage (0.2-0.6g/L), initial MB concentration (10-30mg/L), and temperature (283-323K) on MB adsorption was done at an equilibrium agitation time of 70 min using Central Composite Design (CCD) of Response Surface Methodology (RSM). MB removal percentage of 94.51% (desirability=0.829) was obtained under the optimal conditions of pH=7.28, dosage=0.47g/L, initial MB concentration= 19.37mg/L and temperature =309.76K. The adsorption onto CS-MgONP fits well with pseudo-second-order kinetics equation and equilibrium data made the best fit with Langmuir isotherm with maximum MB uptake capacity of 163.87mg/g. |
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| کلیدواژه‌های انگلیسی مقاله |
Magnesium oxide nanoparticles,Chitosan,Dyes, Nano-adsorbents,Kinetics,equilibrium |
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| نویسندگان مقاله |
Venkata Ratnam Myneni |
Department of Chemical Engineering, Erode Sengunthar Engineering College, Tamil Nadu, INDIA
Nagamalleswara Rao Kanidarapu |
CDMM, Vellore Institute of Technology, Vellore, Tamil Nadu, INDIA
Meena Vangalapati |
Department of Chemical Engineering, A.U. College of Engineering, Vizag, A.P, INDIA
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| نشانی اینترنتی |
https://ijcce.ac.ir/article_36342_96cb6c5c339a4eedc18c8fceabf3b914.pdf |
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| زبان مقاله منتشر شده |
en |
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